Cation Tests

IGCSE Edexcel Chemistry
2.47 Tests for NH4+, Cu2+, Fe2+, Fe3+
Key Concept: Sodium hydroxide forms characteristic precipitates with some metal ions and releases ammonia from ammonium ions.

Section A: Observations

1. Describe the test and positive result for ammonium ions. [2]
2. State the precipitate color formed with sodium hydroxide for: Cu2+, Fe2+, Fe3+. [3]
3. Iron(II) hydroxide changes color on standing in air. What happens and why? [2]

Total marks: 7

Mark Scheme

1. Add NaOH and warm; ammonia gas released; turns damp red litmus paper blue [2]
2. Cu2+ blue ppt, Fe2+ green ppt, Fe3+ brown ppt [3]
3. Green ppt turns brown as Fe2+ oxidises to Fe3+ in air [2]